Advanced polymeric matrix utilizing nanostructured bismuth and tungsten oxides for gamma rays shielding
Hamoud Kassim, Saad Aldawood, Saradh Prasad, Nassar N. Asemi, Aziz A. Aziz, Mohamad S. AlSalhi
Abstract
In this study, the shielding properties of novel polymer composites, developed by integrating glycidyl methacrylate with nanoparticles of bismuth oxide (Bi 2 O 3 ) and tungsten oxide (WO 3 ), were explored. The ability of the composites to attenuate gamma radiation was evaluated by measuring the emissions from Ba-133, Co-60, Cs-137, and Na-22. X-ray diffraction (XRD) spectra were obtained for both the pure polymer glycidyl methacrylate and the samples containing nanostructures of Bi 2 O 3 , Bi 2 O 3 /WO 3 , and WO 3 , and scanning electron microscopy (SEM) was used to analyze the samples. The incorporation of Bi 2 O 3 and WO 3 nanoparticles into the polymer glycidyl methacrylate matrix significantly enhanced the composites' ability to attenuate gamma radiation, as demonstrated by the increased linear and mass attenuation coefficients. The results showed good agreement between the experiment and the XCOM database. The composites exhibited significant efficiency in attenuating lower-energy gamma rays, which is particularly advantageous in the medical and nuclear industries.