Halogen-bond-assisted radical activation of glycosyl donors enables mild and stereoconvergent 1,2-cis-glycosylation
Chen Zhang, Hao Zuo, Ga Young Lee, Yike Zou, Qiu-Di Dang, K. N. Houk, Dawen Niu
Topics & Concepts
ChemistryGlycosylGlycosylationNucleophileStereoselectivityGlycosidic bondElectrophileLewis acids and basesCombinatorial chemistryGlycosyl donorGlycalHalogenPhotoredox catalysisStereochemistryCatalysisOrganic chemistryPhotocatalysisAlkylBiochemistryEnzymeCarbohydrate Chemistry and SynthesisLegume Nitrogen Fixing SymbiosisSulfur-Based Synthesis Techniques