Bias‐Free Solar Water Splitting by Tetragonal Zircon BiVO<sub>4</sub> Nanocrystal Photocathode and Monoclinic Scheelite BiVO<sub>4</sub> Nanoporous Photoanode
Xizhuang Liang, Peng Wang, Fengxia Tong, Xiaolei Liu, Cong Wang, Min‐Rui Wang, Qianqian Zhang, Zeyan Wang, Yuanyuan Liu, Zhaoke Zheng, Ying Dai, Baibiao Huang
Abstract
Abstract p‐type tetragonal zircon BiVO 4 nanocrystal photocathodes (P‐BVO) and n‐type monoclinic scheelite BiVO 4 nanoporous photoanodes (N‐BVO) are prepared by a hydrothermal method and an electrochemical synthesis method, respectively. Pt nanoparticles and cobalt‐phosphate (Co‐Pi) as co‐catalysts are loaded by an electrodeposition way to improve the photoelectrochemical (PEC) performance of BiVO 4 (BVO) electrodes. After modification, a monochromatic incident photon‐to‐current conversion efficiency (IPCE) of P‐BVO/Pt at 360 nm is improved by 2.2 times, and the highest IPCE of N‐BVO/Co‐Pi at 440 nm is increased by 1.7 times. The calculated electron‐hole separation yield and the charge carrier injection yield of N‐BVO/Co‐Pi at 1.23 V RHE are further improved to 80% and 86%, respectively. The surface modification also results in the latest ≈0.2% half‐cell solar‐to‐hydrogen energy conversion efficiency (HC‐STH) for a P‐BVO/Pt photocathode and a higher ≈1.16% half‐cell applied bias photon‐to‐current conversion efficiency (ABPE) for an N‐BVO/Co‐Pi photoanode. Furthermore, the prepared photoelectrodes are proved to have excellent stability for water splitting. Above all, a tandem‐type PEC cell containing the newly developed P‐BVO/Pt photocathode and an N‐BVO/Co‐Pi photoanode is built for the first time, which evolves H 2 and O 2 at a stoichiometric ratio of 2:1 with a bias‐free STH of 0.14%.