Litcius/Paper detail

Modeling the effect of prior austenite grain size on bainite formation kinetics

Daniel dos Santos Avila, S.E. Offerman, María J. Santofimia

2024Acta Materialia32 citationsDOIOpen Access PDF

Abstract

While experiments show that refining the prior austenite grain size can either accelerate or decelerate bainite formation in steels, kinetic models based on the successive nucleation of bainitic ferrite subunits can only predict an acceleration. In this work we develop a physically-based model for bainite kinetics assuming a displacive growth mechanism which is able to reproduce both faster and slower bainite formation kinetics induced by austenite grain refinement. A theoretical analysis of the model and comparison against published experimental data show that slower kinetics for smaller grains is favored as the difference between the activation energy for grain boundary and autocatalytic nucleation of bainite increases, and as the austenite grain refinement results in finer bainite sub-units. We also theoretically analyze the density of initially present potential nucleation sites for bainite and show that the values of density used in other published bainite nucleation models are mostly underestimated. After using physically consistent values for the density of potential nucleation sites, we were able to calculate the apparent lengthening rate of bainite sheaves which were in line with experimentally measured lengthening rates.

Topics & Concepts

BainiteNucleationMaterials scienceAusteniteAutocatalysisGrain sizeMetallurgyKineticsFerrite (magnet)Grain boundaryKinetic energyThermodynamicsMicrostructureComposite materialPhysicsQuantum mechanicsMicrostructure and Mechanical Properties of SteelsMagnetic Properties and ApplicationsHydrogen embrittlement and corrosion behaviors in metals