Electrochemical deconstructive functionalization of arylcycloalkanes <i>via</i> fragmentation of anodically generated aromatic radical cations
Hussain A. Maashi, Abdulrahman H. Husayni, James Harnedy, Louis C. Morrill
Abstract
the fragmentation of anodically generated aromatic radical cations. A diverse range of deconstructive functionalization processes is described, including discussion on the electrochemical reaction conditions employed, scope and limitations, and reaction mechanisms, in addition to highlighting future opportunities in this burgeoning area of sustainable synthesis.
Topics & Concepts
Surface modificationElectrochemistryFragmentation (computing)ChemistryRadical ionPhotochemistryCombinatorial chemistryElectrodeOrganic chemistryIonPhysical chemistryComputer scienceOperating systemRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsCyclopropane Reaction Mechanisms