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Synthesis, Antimicrobial Activity, Molecular Docking and DFT Study: Aryl‐Carbamic Acid 1‐Benzyl‐1 <i>H</i> ‐[1,2,3]Triazol‐4‐ylmethyl Esters

Naveen Naveen, Ram Kumar Tittal, Ghule D. Vikas, Poonam Rani, Kashmiri Lal, Ashwani Kumar

2020ChemistrySelect34 citationsDOI

Abstract

Abstract Bioactive carbamate‐1,4‐disubstituted 1,2,3‐triazole hybrid molecules were synthesized and characterized in high yield from carbamate‐linked terminal alkynes and in situ generated azides using Cell‐CuI‐NPs as heterogeneous catalysts via CuAAC reaction. The synthesized compound 8 demonstrated better antibacterial activity with MIC: 0.0077 μmol mL −1 for each bacterial strain E. coli , S. epidermidis and B. subtilis as compared to reference drug Norfloxacin (MIC: 0.0098 μmol mL −1 ). Also, the antifungal activity of compound 8 with MIC: 0.0077 μmol mL −1 for fungal strain C. albicans was found superior among all synthesized compounds and even better than reference drug Fluconazole with MIC: 0.0102 μmol mL −1 . The biological activity results were supported by molecular docking as well as DFT study.

Topics & Concepts

ChemistryAntimicrobialAntibacterial activityArylFluconazoleStereochemistry1,2,3-TriazoleDocking (animal)CarbamateCandida albicansCombinatorial chemistryTriazoleAzoleAntifungalOrganic chemistryBacteriaAlkylMicrobiologyBiologyMedicineNursingGeneticsClick Chemistry and ApplicationsSynthesis and Biological EvaluationSynthesis and Catalytic Reactions
Synthesis, Antimicrobial Activity, Molecular Docking and DFT Study: Aryl‐Carbamic Acid 1‐Benzyl‐1 <i>H</i> ‐[1,2,3]Triazol‐4‐ylmethyl Esters | Litcius