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Recent Developments in Layered Double Hydroxides as Anticorrosion Coatings

Alessandra Varone, Riccardo Narducci, Alessandra Palombi, Subhan Rasulzade, Roberto Montanari, M. Richetta

2025Materials6 citationsDOIOpen Access PDF

Abstract

To date, one of the main problems associated with the engineering application of metallic materials is corrosion protection. To increase their durability and reduce damage, a variety of protection methods have been studied and applied. In recent decades, coating techniques have become increasingly important. Among these coatings, Layered Double Hydroxides (LDHs) have shown unique properties, such as ion exchange, high adhesion, and hydrophobicity, particularly useful for biomedical applications. In this review, after a detailed exposition of the LDHs' synthesis processes, the most recent corrosion protection methods are illustrated. Intercalation of corrosion inhibitors and release kinetics of intercalates are presented. Although this work is mainly focused on laboratory-scale investigations and fundamental research, the problems inherent to large-scale industrial manufacturing and application are outlined and briefly discussed.

Topics & Concepts

Layered double hydroxidesCorrosionMaterials scienceDurabilityCoatingIntercalation (chemistry)MetallurgyNanotechnologyComposite materialChemical engineeringEngineeringChemistryHydroxideInorganic chemistryLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and ApplicationsInorganic Chemistry and Materials