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Ion Substitution Strategy toward Spectral Tunability of Environmentally Friendly Rare Earth Sulfide Lattices for Radiative Cooling

Le Wang, Gongxun Bai, Peng Xue, Shuqin Zhang, Liang Chen, Shiqing Xu

2023ACS Sustainable Chemistry & Engineering13 citationsDOI

Abstract

Radiation cooling technology can effectively reduce the energy transmission of the sun to the building during the day, thus playing a certain positive role in alleviating the urban heat island effect and reducing energy consumption. In this study, red Nd-doped γ-Ce 2 S 3 and orange La-doped γ-Ce 2 S 3 were prepared by the green synthesis method, and their morphologies and optical properties were systematically studied. The color film produced by mixing the prepared microcrystalline powder with poly(vinylidene fluoride-hexafluoro propylene) at a certain proportion has near-infrared reflectivity and superior environmental resistance, achieving effective cooling of 3–6 °C when applied to the building surface. This study expands ideas for energy-efficient building materials and enriches the path to a carbon neutral sustainable future.

Topics & Concepts

MicrocrystallineMaterials scienceEnvironmentally friendlyOptoelectronicsDopingIonChemical engineeringInfraredNanotechnologyEngineering physicsOpticsChemistryOrganic chemistryBiologyEcologyPhysicsEngineeringCrystallographyThermal Radiation and Cooling TechnologiesUrban Heat Island MitigationOptical properties and cooling technologies in crystalline materials