Transition-metal-free regioselective and stereoselective C(sp<sup>2</sup>)–C(sp<sup>3</sup>) coupling of enamides with ethers or alkanes <i>via</i> photoredox-catalyzed cross-dehydrogenative coupling reactions
Ji‐Yu Tao, Yingxue Wang, Qinghong Zhang, Kun Ni, Tong‐Hao Zhu, Kai Zhao
Abstract
A regio- and stereoselective C(sp 2 )–C(sp 3 ) coupling of enamides with ethers or alkanes via photoredox-catalyzed cross-dehydrogenative coupling reactions is developed under environmentally friendly conditions.
Topics & Concepts
StereoselectivityRegioselectivityChemistryCatalysisCoupling reactionCoupling (piping)Transition metalMetalStereochemistryMedicinal chemistryOrganic chemistryMaterials scienceMetallurgyCatalytic C–H Functionalization MethodsSulfur-Based Synthesis TechniquesRadical Photochemical Reactions