Litcius/Paper detail

Van der Waals Heterostructure Mid-Infrared Emitters with Electrically Controllable Polarization States and Spectral Characteristics

Po‐Liang Chen, Tian-Yun Chang, Pei-Sin Chen, Alvin Hsien‐Yi Chan, Adzilah Shahna Rosyadi, Yen-Ju Lin, Pei‐Yu Huang, Jiaxin Li, Wei-Qing Li, Chia‐Jui Hsu, Neil Na, Yao-Chang Lee, Ching‐Hwa Ho, Chang‐Hua Liu

2023ACS Nano17 citationsDOI

Abstract

Modern infrared (IR) microscopy, communication, and sensing systems demand control of the spectral characteristics and polarization states of light. Typically, these systems require the cascading of multiple filters, polarization optics, and rotating components to manipulate light, inevitably increasing their sizes and complexities. Here, we report two-terminal mid-infrared (mid-IR) emitters, in which tuning the polarity of the applied bias can switch their emission peak wavelengths and linear polarization states along two orthogonal orientations. Our devices are composed of two back-to-back p–n junctions formed by stacking anisotropic light-emitting materials, black phosphorus and black arsenic–phosphorus with MoS 2 . By controlling the crystallographic orientations and engineering the band profile of heterostructures, the emissions of two junctions exhibit distinct spectral ranges and polarization directions; more importantly, these two electroluminescence (EL) units can be independently activated, depending on the polarity of the applied bias. Furthermore, we show that when operating our emitter under the polarity-switched pulse mode, the time-averaged EL exhibits the characteristics of broad spectral coverage, encompassing the entire first mid-IR atmospheric window (λ: 3–5 μm), and electrically tunable spectral shapes.

Topics & Concepts

van der Waals forceMaterials scienceOptoelectronicsInfraredPolarization (electrochemistry)HeterojunctionOpticsPhysicsChemistryMoleculeQuantum mechanicsPhysical chemistry2D Materials and ApplicationsSemiconductor Quantum Structures and DevicesThermal Radiation and Cooling Technologies