Litcius/Paper detail

Low-cost porous transport layers for water electrolysis cells with polymer electrolyte membranes

Hiroaki Wakayama

2024Materials Research Express11 citationsDOIOpen Access PDF

Abstract

Abstract Proton exchange membrane (PEM) water electrolysis has advantages over other methods of producing green hydrogen such as its excellent response to power input fluctuations; wide operating range of current density; ease of production of high-pressure, high-purity hydrogen; and high durability. However, the conventional precious metal coatings used on the bipolar plates (BPPs) and porous transport layers (PTLs) of the PEM water electrolysis cell to prevent their oxidation are problematic because of their high cost; indeed, the BPPs and PTLs combined are the largest contributor (50%–70%) to the total cost of PEM water electrolysis stacks. Here, the Pt-coated PTL on the oxygen electrode side of a PEM water electrolysis cell was replaced with one with an alternative low-cost material coating (Ti 4 O 7 or NiTiP), and the water electrolysis characteristics of the system were evaluated. We found that Ti 4 O 7 , but not NiTiP, functioned as a conductive, corrosion-resistant PTL coating in the PEM water electrolysis cell.

Topics & Concepts

Polymer electrolyte membrane electrolysisElectrolysisProton exchange membrane fuel cellElectrolysis of waterMaterials scienceElectrolyteHigh-pressure electrolysisCoatingWater transportElectrolytic cellChemical engineeringHydrogen productionHigh-temperature electrolysisHydrogenMembrane electrode assemblyPorosityCorrosionElectrodeComposite materialChemistryFuel cellsEnvironmental engineeringWater flowEnvironmental scienceOrganic chemistryEngineeringPhysical chemistryHybrid Renewable Energy SystemsFuel Cells and Related MaterialsAdvanced Battery Technologies Research