Litcius/Paper detail

Microsecond Photoluminescence and Photoreactivity of a Metal-Centered Excited State in a Hexacarbene–Co(III) Complex

Simon Kaufhold, Nils W. Rosemann, Pavel Chábera, Linnea Lindh, Iria Bolaño Losada, Jens Uhlig, Torbjörn Pascher, Daniel Strand, Kenneth Wärnmark, Arkady Yartsev, Petter Persson

2021Journal of the American Chemical Society95 citationsDOIOpen Access PDF

Abstract

complex. Singlet oxygen quenching supports the assignment of the emitting state as a triplet metal-centered state and underlines its capability of driving excitation energy transfer processes.

Topics & Concepts

ChemistryMicrosecondPhotoluminescencePhotochemistryExcited stateLuminescencePhosphorescenceCobaltSpectroscopySinglet stateMetal carbonylMetalQuenching (fluorescence)ExcitationQuantum yieldTriplet stateFluorescenceMoleculeInorganic chemistryAtomic physicsOptoelectronicsOrganic chemistryPhysicsAstronomyElectrical engineeringQuantum mechanicsEngineeringN-Heterocyclic Carbenes in Organic and Inorganic ChemistryOrganic Light-Emitting Diodes ResearchCatalytic C–H Functionalization Methods