Macrocycle polymeric networks based on a chair-like calix[4]pyrrole for the rapid and efficient adsorption of iodine from water
Z. Zheng, Qiuyuan Lin, Linhuang Xie, Xiaolong Chen, Huan‐Xiang Zhou, Kunhua Lin, Dengsong Zhang, Xiaodong Chi, Jonathan L. Sessler, Hongyu Wang
Abstract
Two macrocycle polymeric networks (MPNs), C[4]P-TEPM and C[4]P-HEPM, were synthesized and found to exhibit iodine uptake capacities of 4.02 and 4.45 g g −1 from a KI/I 2 solution, respectively. These values are among the highest reported for iodine adsorbent materials.
Topics & Concepts
IodineAdsorptionPyrroleChemistryPolymer chemistryNuclear chemistryOrganic chemistryCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and Complexes