Asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B
Xiaoqing Lu, Yuanyou Qiu, Baochao Yang, Haibing He, Shuanhu Gao
Abstract
-promoted photoenolization/Diels-Alder, dehydration, and aromatization reactions. This asymmetric strategy provides a scalable route to prepare target molecules and their derivatives for further biological studies.
Topics & Concepts
Total synthesisStereochemistryChemistryBioactive Compounds and Antitumor AgentsAxial and Atropisomeric Chirality SynthesisChemical synthesis and alkaloids