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Recent Advances in Metal‐Catalyzed C−H Bond Functionalization Reactions of Sulfoxonium Ylides

Pratiksha Bhorali, Sabera Sultana, Sanjib Gogoi

2022Asian Journal of Organic Chemistry58 citationsDOI

Abstract

Abstract In recent years, the transition‐metal‐catalyzed functionalization reactions of sulfoxonium ylides have been explored extensively because of their usefulness as carbene‐transfer agents, since they can produce metal carbenes through metal catalysis. Moreover, they are safer and have the advantages of simple handling and good stability over their other counterparts like diazo‐compounds. This review article attempts to highlight the recent advances in the metal‐catalyzed C−H functionalization of sulfoxonium ylides.

Topics & Concepts

ChemistrySurface modificationCarbeneDiazoCatalysisCombinatorial chemistryMetalOrganic chemistryPhysical chemistryCatalytic C–H Functionalization MethodsCyclopropane Reaction MechanismsSynthesis and Catalytic Reactions
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