Impact of counter anions on spin-state switching of manganese(<scp>iii</scp>) complexes containing an azobenzene ligand
Subrata Ghosh, Sukanya Bagchi, Sujit Kamilya, Sakshi Mehta, Debopam Sarkar, Radovan Herchel, Abhishake Mondal
Abstract
= 0.002-0.195). Spectroelectrochemical investigations revealed the quasi-reversible reduction and oxidation of the manganese(III) center to manganese(II) and manganese(IV), respectively. A detailed theoretical calculation at the DFT and CASSCF level of theory was carried out to better understand the magneto-structural correlation.
Topics & Concepts
ChemistryCrystallographyIsostructuralManganeseLigand (biochemistry)AzobenzeneOctahedronSpin statesIonCationic polymerizationOxidation stateStereochemistryCrystal structureInorganic chemistryMetalMoleculeOrganic chemistryReceptorBiochemistryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal complexes synthesis and properties