Skeletal rearrangement through photocatalytic denitrogenation: access to C-3 aminoquinolin-2(1<i>H</i>)-ones
Swati Singh, Gopal Chakrabortty, Sudipta Raha Roy
Abstract
)-one backbone, which demonstrates remarkable tolerance of sensitive functional groups. The control experiments showed that the triazoline intermediate plays a significant role in the formation of the product. The spectroscopic investigation further defined the potential reaction pathways.
Topics & Concepts
ChemistryAmine gas treatingCombinatorial chemistryMoleculeFunctional groupCascadeStereochemistryOrganic chemistryChromatographyPolymerRadical Photochemical ReactionsSynthesis and Catalytic ReactionsCatalytic C–H Functionalization Methods