Covalent Organic Frameworks with Tailored Functionalities for Modulating Surface Potentials in Triboelectric Nanogenerators
Chao Lin, Linhai Sun, Xutong Meng, Xin Yuan, Cheng‐Xing Cui, Huijie Qiao, Pengjing Chen, Siwen Cui, Lipeng Zhai, Liwei Mi
Abstract
Designing materials with high triboelectric is an efficient way of improving output performance of triboelectric nanogenerators (TENGs). Herein, we synthesized a series of covalent organic frameworks (COFs) with similar skeletons but various functional groups ranging between electron-donating and electron-withdrawing. These COFs form an ideal platform for clarifying the contribution of each group to TENG performance because the pore wall is perturbed in a predesigned manner. Kelvin probe force microscopy and computational data suggest that surface potentials and electron affinities of COFs can be improved by introducing electron-donating or withdrawing groups, with the highest values observed for fluorinated COF. The TENG with fluorinated COF delivered an output voltage and current of 420 V and 64 μA, respectively, which are comparable to other reported materials. This strategy can be used to efficiently screen suitable frameworks as TENG materials with excellent output performance.