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A pillar[5]arene noncovalent assembly boosts a full-color lanthanide supramolecular light switch

Wei‐Lei Zhou, Xianyin Dai, Wenjing Lin, Yong Chen, Yu Liu

2023Chemical Science41 citationsDOIOpen Access PDF

Abstract

alternant UV/vis light irradiation due to the conformation-dependent photochromic energy transfer between the lanthanide and the open/closed-ring of diarylethene. Ultimately, the prepared lanthanide supramolecular switch was successfully applied to anti-counterfeiting through the use of intelligent multicolored writing inks, and presents new opportunities for the design of advanced stimuli-responsive on-demand color tuning with lanthanide luminescent materials.

Topics & Concepts

LanthanideSupramolecular chemistryDiaryletheneLuminescencePhotochemistrySupramolecular assemblySupramolecular polymersMaterials scienceAqueous solutionChemistryPhotochromismCrystal structureCrystallographyPhysical chemistryIonOrganic chemistryOptoelectronicsLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry
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