Synthesis, structure, and properties of helical bis-Zn(<scp>ii</scp>) complexes of hexapyrrolic ligands
Pinky Chauhan, Poornenth Pushpanandan, Mangalampalli Ravikanth
Abstract
Bis(3-pyrrolyl BODIPY)s were used to prepare rare examples of hexapyrrolic ligands by demasking BF 2 units. The hexapyrrolic ligands, without isolating, were used to prepare novel examples of double-stranded bis-Zn( ii ) helicate complexes.
Topics & Concepts
ChemistryStereochemistryCombinatorial chemistryBODIPYCrystallographyFluorescencePhysicsQuantum mechanicsMetal-Organic Frameworks: Synthesis and ApplicationsPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials