Photobiocatalytic Oxyfunctionalization with High Reaction Rate using a Baeyer–Villiger Monooxygenase from <i>Burkholderia xenovorans</i> in Metabolically Engineered Cyanobacteria
Elif Erdem, Lenny Malihan‐Yap, Leen Assil‐Companioni, Hanna C. Grimm, Giovanni Davide Barone, Carole Serveau‐Avesque, Agnès Amouric, Katia Duquesne, Véronique de Berardinis, Yagut Allahverdiyeva, Véronique Alphand, Robert Kourist
Abstract
underline the usefulness of oxygenic cyanobacteria as a chassis for enzymatic oxidation reactions. The photosynthetic oxygen evolution can contribute to alleviating the highly problematic oxygen mass-transfer limitation of oxygen-dependent enzymatic processes.
Topics & Concepts
ChemistryCyclohexanoneSynechocystisMonooxygenaseCatalysisPhotochemistryStereochemistryCombinatorial chemistryOrganic chemistryEnzymeBiochemistryMutantGeneCytochrome P450Enzyme Catalysis and ImmobilizationPhotosynthetic Processes and MechanismsAlgal biology and biofuel production