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Preparation and surface characteristics of phosphoric acid‐activated carbon from coconut shell in air

Daisuke Higai, Zhebin Huang, Eika W. Qian

2020Environmental Progress & Sustainable Energy37 citationsDOI

Abstract

Abstract A process of chemical activation with phosphoric acid from coconut shell in air to produce activated carbon was developed. The effects of various preparation parameters on the porous texture and surface characteristics were investigated by means of the nitrogen physisorption, Fourier transform‐infrared spectra (FT‐IR), and X‐ray photoelectron spectroscopy (XPS). The adsorption capacities of activated carbon for chromium, lithium, and cesium were also investigated. The surface modification of activated carbon using nitric acid was performed to enhance the adsorption capacities, and the relationship between the adsorption capacities and the surface functional groups was investigated. The oxygen‐containing functional groups on the surface of an activated carbon played a more important role than its textural structure in adsorption of metal ions, especially cesium ion.

Topics & Concepts

Activated carbonPhosphoric acidPhysisorptionAdsorptionNitric acidFourier transform infrared spectroscopyX-ray photoelectron spectroscopyChemistryInorganic chemistrySurface modificationCarbon fibersMaterials scienceChemical engineeringOrganic chemistryPhysical chemistryComposite materialEngineeringComposite numberAdsorption and biosorption for pollutant removalRadioactive element chemistry and processingExtraction and Separation Processes
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