Spin-state switching: chemical modulation and the impact of intermolecular interactions in manganese(<scp>iii</scp>) complexes
Sukanya Bagchi, Sujit Kamilya, Sakshi Mehta, Subhankar Mandal, Arka Bandyopadhyay, Awadhesh Narayan, Subrata Ghosh, Abhishake Mondal
Abstract
This work unravels the magneto-structural correlation of mononuclear manganese( iii ) complexes via chemical modulation, showcasing the role of ligand substitutions, counter anion, and intermolecular interactions on spin-state switching.
Topics & Concepts
ChemistryCrystallographyManganeseSpin transitionSpin statesLigand (biochemistry)OctahedronSpin crossoverCooperativityEthylenediamineMoleculeIntermolecular forceSalicylaldehydeSingle crystalCrystal structureInorganic chemistrySchiff baseBiochemistryOrganic chemistryReceptorMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies