A tertiary phosphine oxide ligand-based recyclable system for the Suzuki–Miyaura and Negishi reactions: evidence for pseudo-homogeneous catalysis
Andrew K. King, Aneelman Brar, Michael Findlater
Abstract
A recyclable palladium catalyst is generated from readily available commercial materials and applied in Suzuki–Miyaura and Negishi coupling reactions. The nature of the catalyst is explored and proposed to be pseudo-homogeneous in nature.
Topics & Concepts
Negishi couplingCatalysisPhosphineLigand (biochemistry)Homogeneous catalysisHomogeneousPalladiumChemistryPhosphine oxideCombinatorial chemistrySuzuki reactionOrganic chemistryMathematicsReceptorCombinatoricsBiochemistryCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques