MXenes: Multifunctional 2D materials for hydrogen evolution, energy storage, and carbon capture applications
Jarosław Serafin, Stefanos Chaitoglou, Ghulam Farid, Yang Ma, Bartosz Dziejarski, Adrià Sánchez, Xavier Vendrell, Roger Amade
Abstract
Ti₃C₂Tₓ MXene was synthesized by selective etching of Ti₃AlC₂ MAX phase using HF. Structural and surface properties were assessed via XRD, Raman, SEM, HRTEM, BET, and XPS, confirming Al removal, interlayer expansion, and functionalization with F, –OH, and = O groups. The resulting MXene exhibited a specific surface area of 26.7 m 2 /g and pore size of 16.2 nm. A single batch was deployed in three applications: as an HER electrocatalyst in 1 M H₂SO₄, achieving −511 mV onset potential, 190 mA cm −2 at −760 mV, and a Tafel slope of 184 mV dec −1 ; as a supercapacitor electrode in 3 M KOH, with areal capacitance of 411.1 mF cm −2 and 86.9 % diffusion-controlled contribution; as a CO₂ adsorbent, achieving uptakes of 0.80 and 0.66 mmol g −1 at 0 °C and 25 °C, respectively. Adsorption data fitted best to the Radke–Prausnitz isotherm, indicating mixed physisorption–chemisorption. A techno-economic analysis yielded a production cost of ~2.83 €/g. These results demonstrate the multifunctionality and scalability of Ti₃C₂Tₓ MXene as a good material for hydrogen generation, energy storage, and carbon capture. • Ti₃C₂Tₓ MXene synthesized via HF etching of Ti₃AlC₂ MAX phase. • Ti₃C₂Tₓ MXene was used in HER, supercapacitor, and CO₂ capture. • Applied in HER electrocatalysis: 190 mA cm −2 at −760 mV vs. RHE. • Delivered 411.1 mF cm −2 areal capacitance in KOH supercapacitors. • Adsorbed 0.80 mmol g −1 CO₂ at 0 °C; Radke–Prausnitz isotherm fit.