Using a simple method to prepare <scp>UiO‐66‐NH<sub>2</sub></scp>/chitosan composite membranes for oil–water separation
Ximei Zhu, Zongxue Yu, Haojie Zeng, Xiaofang Feng, Yuchuan Liu, Kunyao Cao, Xuyang Li, Runxuan Long
Abstract
Abstract Chitosan (CS) was used as a cross‐linking agent to modify UiO‐66‐NH 2 , and the modified UiO‐66‐NH 2 was fixed on the mixed cellulose membrane (MCE) through vacuum filtration technology to prepare a new type of membrane. The membrane exhibited excellent hydrophilicity in the air and excellent super‐oleophobic performance underwater, and effectively separated various oil–water emulsions. When separating petroleum ether‐water emulsion, the filtration flux of the modified membrane was 2000 L m −2 h −1 higher than that of MCE, and the separation efficiency can reach more than 95%. After 10 cycles, the flux of the modified membrane was about four times of that MCE, which was 500 L m −2 h −1 . Most importantly, the membrane still maintained underwater superoleophobicity in the environment of strong acid, strong base, and salt solution.