Tuning primary and secondary coordination spheres of ruthenium complexes for the homogeneous water oxidation reaction: a perspective from catalytic activity and overpotential
Hao-Chen Ma, Shun-Chien Hsiao, Yu‐Heng Wang
Abstract
The impact of primary and secondary coordination spheres on Ru-based water oxidation catalysts is analyzed from kinetics (turnover frequency, TOF) and thermodynamics (overpotential, η ) perspectives.
Topics & Concepts
OverpotentialCatalysisRutheniumPrimary (astronomy)HomogeneousSPHERESChemistryKineticsInorganic chemistryChemical engineeringOrganic chemistryThermodynamicsElectrochemistryPhysical chemistryPhysicsElectrodeQuantum mechanicsAstronomyEngineeringElectrocatalysts for Energy ConversionMetal complexes synthesis and propertiesCatalytic Processes in Materials Science