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Advances in SnO<sub>2</sub> for Efficient and Stable n–i–p Perovskite Solar Cells

So Yeon Park, Kai Zhu

2022Advanced Materials440 citationsDOIOpen Access PDF

Abstract

Abstract Perovskite solar cells (PSCs) based on the regular n–i–p device architecture have reached above 25% certified efficiency with continuously reported improvements in recent years. A key common factor for these recent breakthroughs is the development of SnO 2 as an effective electron transport layer in these devices. In this article, the key advances in SnO 2 development are reviewed, including various deposition approaches and surface treatment strategies, to enhance the bulk and interface properties of SnO 2 for highly efficient and stable n–i–p PSCs. In addition, the general materials chemistry associated with SnO 2 along with the corresponding materials challenges and improvement strategies are discussed, focusing on defects, intrinsic properties, and impact on device characteristics. Finally, some SnO 2 implementations related to scalable processes and flexible devices are highlighted, and perspectives on the future development of efficient and stable large‐scale perovskite solar modules are also provided.

Topics & Concepts

Materials sciencePerovskite (structure)NanotechnologyChemical engineeringEngineering physicsEngineeringPerovskite Materials and ApplicationsChalcogenide Semiconductor Thin FilmsZnO doping and properties
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