Preparation of SnIn4S8/TiO2 Nanotube Photoanode and Its Photocathodic Protection for Q235 Carbon Steel Under Visible Light
Hong Li, Weizhe Song, Xingqiang Cui, Yanhui Li, Baorong Hou, Lianjun Cheng, Pengfei Zhang
Abstract
Abstract TiO 2 is an attractive semiconductor suitable for photocathodic protection, but its weak absorption of visible light and low quantum yield limit its usage. Here, a new heterostructured SnIn 4 S 8 nanosheet/TiO 2 nanotube photoanode was prepared and its photocathodic protection performance was analyzed. SnIn 4 S 8 nanosheets were uniformly deposited on the surface of the TiO 2 nanotube via a solvothermal treatment. The SnIn 4 S 8 / TiO 2 composite exhibited better photocathodic protection performance compared with pure TiO 2 nanotubes, owing to its good visible-light response and photogenerated carrier separation efficiency. Moreover, the composite exhibited a maximum photocurrent density of 100 μA cm −2 for a 6 h solvothermal reaction under visible light irradiation. The negative shift of the photoinduced potential of Q235 carbon steel connected to the composite could reach 0.45 V versus SCE. Therefore, the SnIn 4 S 8 /TiO 2 composite can offer efficient photocathodic protection for Q235 carbon steel against corrosion in 3.5 wt% NaCl solution. This work provides a new approach for the development of high-efficient photoanode materials for the photocathodic protection of metals.