Dinuclear helicate or mononuclear pincer lanthanide complexes from one ligand: stereo-controlled assembly and catalysis
Ran Chen, Qianqian Yan, Shao‐Jun Hu, Xiaoqing Guo, Li‐Xuan Cai, Dan‐Ni Yan, Li‐Peng Zhou, Qing‐Fu Sun
Abstract
By varying the metal/ligand ratio, either dinuclear triple helicate or mononuclear pincer can be stereo-selectively obtained from the same chiral ligand. Their catalytic properties have been demonstrated with the asymmetric FC alkylation reactions.
Topics & Concepts
ChemistryLigand (biochemistry)Pincer movementLanthanideCatalysisCombinatorial chemistryLinkerPincer ligandAlkylationMetalStereochemistryPolymer chemistryOrganic chemistryReceptorBiochemistryIonOperating systemComputer scienceSupramolecular Chemistry and ComplexesOrganometallic Complex Synthesis and CatalysisMagnetism in coordination complexes