Oxygen-Vacancy-Rich Cu<sub>2</sub>O Hollow Nanocubes for Nitrate Electroreduction Reaction to Ammonia in a Neutral Electrolyte
Xiaohui Wang, Zhengmin Wang, Qing‐Ling Hong, Ze‐Nong Zhang, Feng Shi, Dong‐Sheng Li, Shu-Ni Li, Yu Chen
Abstract
The electrocatalytic nitrate reduction reaction (NO3–-ERR) to ammonia (NH3) is a promising strategy for NH3 production. Cu-based nanomaterials have been regarded as a kind of effective NO3–-ERR catalysts. In this work, high-quality hollow Cu2O nanocubes (Cu2O h-NCs) are facilely synthesized by a simple one-step reduction method. The as-prepared Cu2O h-NCs reveal high selectivity and activity for NO3–-ERR, which is ascribed to abundant oxygen vacancies, high surface area, hollow architecture, low mass transfer resistance, and strong adsorbing ability toward NO3–. In fact, Cu2O h-NCs can achieve a Faradic efficiency of 92.9% and an NH3 yield of 56.2 mg h–1 mgcat–1 for NH3 production at −0.85 V (vs RHE) potential, which exceeds those of other transition-metal-based NO3–-ERR electrocatalysts.