Hydrogen-bonded organic framework with tailored pores prepared by enlarging the core size for high-performance Xe/Kr separation
Zhen Yuan, Liangji Chen, Xin Zhou, Lu Li, Yunbin Li, Yisi Yang, Zhiqi Zhou, Yanting Chen, Shengchang Xiang, Banglin Chen, Zhangjing Zhang
Abstract
A pore engineering optimized strategy by enlarging the core size of rigid monomers is proposed to increase the pore size of benzene cyanide-based HOFs, resulting in the highest performing HOF material for Xe/Kr separation.
Topics & Concepts
BenzeneMonomerCore (optical fiber)HydrogenMaterials scienceChemical engineeringNanotechnologyPolymer chemistryComposite materialChemistryOrganic chemistryPolymerEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsGas Sensing Nanomaterials and Sensors