High‐Density and Thermally Stable Palladium Single‐Atom Catalysts for Chemoselective Hydrogenations
Ying Ma, Yujing Ren, Yanan Zhou, Wei Liu, Walid Baaziz, Ovidiu Ersen, Cuong Pham‐Huu, Mark Greiner, Wei Chu, Aiqin Wang, Tao Zhang, Yuefeng Liu
Abstract
Abstract Single‐atom catalysts (SACs) have shown superior activity and/or selectivity for many energy‐ and environment‐related reactions, but their stability at high site density and under reducing atmosphere remains unresolved. Herein, we elucidate the intrinsic driving force of a Pd single atom with high site density (up to 5 wt %) under reducing atmosphere, and its unique catalytic performance for hydrogenation reactions. In situ experiments and calculations reveal that Pd atoms tend to migrate into the surface vacancy‐enriched MoC surface during the carburization process by transferring oxide crystals to carbide crystals, leading to the surface enrichment of atomic Pd instead of formation of particles. The Pd 1 /α‐MoC catalyst exhibits high activity and excellent selectivity for liquid‐phase hydrogenation of substituted nitroaromatics (>99 %) and gas‐phase hydrogenation of CO 2 to CO (>98 %). The Pd 1 /α‐MoC catalyst could endure up to 400 °C without any observable aggregation of single atoms.