A dense 3d–4f metal–organic framework with “gas pockets” for highly efficient CH<sub>4</sub>/N<sub>2</sub>separation
Li‐Min Zhu, Wenliang Li, Tianran Li, Linping Shi, Liting Li, Zhao‐Quan Yao, Hongliang Huang, Jiong‐Peng Zhao, Fu‐Chen Liu
Abstract
A pillar-layered dense 3d–4f MOF shows high IAST selectivity for CH 4 /N 2 owing to the enhancement of the interactions between the MOF and CH 4 by the heteroatoms of the pillars.
Topics & Concepts
HeteroatomPillarSelectivityMaterials scienceMetal-organic frameworkMetalSeparation (statistics)Chemical engineeringNanotechnologyPhysical chemistryChemistryMetallurgyOrganic chemistryRing (chemistry)CatalysisComputer scienceMechanical engineeringEngineeringAdsorptionMachine learningMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsInorganic Fluorides and Related Compounds