Carbonylative transformation of aryl halides and strong bonds via cheap metal catalysts and sustainable technologies
Maolin Yang, Yukun Liu, Xin Qi, Yanhua Zhao, Xiao‐Feng Wu
Abstract
The development of catalytic carbonylation reactions has increased considerably. Although many reviews/chapters/books on carbonylation reactions have been published, summaries on cheap metal-catalyzed catalytic carbonylation reactions of aryl halides and other chemical bonds with high dissociation energy C-Y (Y = O, N, H) are still very rare. Focusing on green and sustainable chemistry, this review summarizes and discusses the achievements on carbonylative transformations of aryl halides (C(sp2)-X) and strong bonds C-Y (Y = O, N, H) based on non-expensive metal catalysts (Co, Mn, Mo, Ni, Fe, Cu), photochemical and electrochemical systems developed in recent decades.
Topics & Concepts
CarbonylationHalideCatalysisArylDissociation (chemistry)ChemistryMetalAryl halidePhotochemistryOrganic chemistryPalladiumCarbon monoxideAlkylCarbon dioxide utilization in catalysisCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling Reactions