One-pot production of diethyl maleate <i>via</i> catalytic conversion of raw lignocellulosic biomass
Zhenping Cai, Rujia Chen, Hao Zhang, Fukun Li, Jinxing Long, Lilong Jiang, Xuehui Li
Abstract
Selective conversion of raw biomass to diethyl maleate was conducted by polyoxometalate ionic liquid [BSmim]CuPW 12 O 40 , where up to 329.6 mg g −1 DEM yield, 70.3 % selectivity, and 20.8% carbon yield were obtained at 170 °C for 4 h and 1 MPa O 2 .
Topics & Concepts
Yield (engineering)Raw materialChemistryCatalysisSelectivityBiomass (ecology)Ionic liquidLignocellulosic biomassOrganic chemistryNuclear chemistryAgronomyHydrolysisMaterials scienceMetallurgyBiologyCatalysis for Biomass ConversionCatalysis and Hydrodesulfurization StudiesLignin and Wood Chemistry