Photocatalytic Reduction of CO2 Over Me (Pt, Pd, Ni, Cu)/TiO2 Catalysts
Oleksandr Shtyka, Radosław Ciesielski, Adam Kêdziora, Waldemar Maniukiewicz, Sergey Dubkov, Д. Г. Громов, Tomasz Maniecki
Abstract
Abstract A series of TiO 2 photocatalysts loaded with various metals (Pt, Pd, Ni, and Cu) were prepared by using the wet impregnation method. Their physicochemical properties were studied by using XRD, BET, TPR-H 2 , FTIR and TPD-NH 3 /CO 2 techniques. The photocatalytic activity of samples was investigated in the gas-phase reduction of carbon dioxide under continuous flow operation mode. Among all investigated catalysts, the Pt and Ni were the most active in terms of the formation rate of methanol. In general, the photocatalytic activity of modified TiO 2 decreased with increasing metal loading and reaction time. The reversible deactivation of photocatalysts was associated with the covering of TiO 2 surface by the reaction products.