Metal- and oxidant-free carbonylation of benzylic and allylic C–H bonds with H<sub>2</sub>O <i>via</i> dual oxidative radical-polar crossover
Xiaona Yang, Bingjie Ren, Hongyu Guo, Rongfang Liu, Rong Zhou
Abstract
A visible-light photocatalytic carbonylation of both benzylic and allylic C–H bonds with H 2 O in a metal-, oxidant-, and additive-free manner via a dual oxidative radical-polar crossover (ORPC) process has been developed.
Topics & Concepts
Allylic rearrangementChemistryOxidative phosphorylationCarbonylationPolarMetalRadicalCrossoverPhotochemistryMedicinal chemistryOrganic chemistryCarbon monoxideBiochemistryCatalysisAstronomyArtificial intelligencePhysicsComputer scienceCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques