A crystalline cyclic (alkyl)(amino)carbene with a 1,1′-ferrocenylene backbone
Julia Volk, Myron Heinz, Michael Leibold, Clemens Bruhn, Tobias Bens, Biprajit Sarkar, Max C. Holthausen, Ulrich Siemeling
Abstract
bond angle is unprecedentedly wide for a CAAC, causing an exceptionally pronounced ambiphilicity. The redox-active backbone opens the door to unconventional metalloradicals and oligoradicals.
Topics & Concepts
AlkylChemistryCarbeneStereochemistryRedoxCyclic peptideCombinatorial chemistryOrganic chemistryCatalysisBiochemistryPeptideN-Heterocyclic Carbenes in Organic and Inorganic ChemistryCatalytic Cross-Coupling ReactionsOrganometallic Complex Synthesis and Catalysis