Carboxylic Acid Functionalization Using Sulfoxonium Ylides as a Carbene Source
Fathima Febin Koothradan, Anusree Suresh Babu, Krishnendu P. Pushpakaran, Arumugam Jayarani, Chinnappan Sivasankar
Abstract
] as a catalyst is reported. The usual carbene source, diazo compounds, failed to produce α-carbonyloxy esters in good yield when compared to sulfoxonium ylides. Various standard spectroscopic and analytical techniques were used to characterize the products formed.
Topics & Concepts
CarbeneChemistrySurface modificationDiazoYield (engineering)CatalysisCarboxylic acidOrganic chemistryCombinatorial chemistryPolymer chemistryComposite materialPhysical chemistryMaterials scienceCyclopropane Reaction MechanismsSynthesis and Catalytic ReactionsCatalytic C–H Functionalization Methods