Selective phase corrosion and cavitation erosion behaviors of various copper alloys in 3.5% NaCl solutions with different pH values
Qining Song, Hui-lin LI, Nan Xu, Zhen-yu JIANG, Gen-yuan ZHANG, Yefeng Bao, Yongfeng Jiang, Lijuan Zhao, Cui-cui JI, Jianhua Zhao, Yanxin Qiao
Abstract
The stability of each phase in nickel aluminum bronze (NAB), manganese aluminum bronze (MAB) and manganese brass (MB) was characterized by scanning Kelvin probe force microscopy (SKPFM). Selective phase corrosion (SPC) and cavitation erosion (CE) behaviors of these materials were studied in 3.5% NaCl solution with different pH values. The results show that the κ phase with the lowest stability is dissolved in the acidic solution (pH 2) for each material. In the neutral solution (pH 6.8), the Al-abundant κ phases in NAB are preserved, whereas the Fe-rich κ phases in MAB and MB are dissolved. In the alkaline solution (pH 12), pitting corrosion occurs at the κ phases in MAB and MB and at the κII phase in NAB. In each solution, NAB possesses the highest CE resistance, followed by MAB and MB. In the acidic solution, SPC remarkably intensifies the CE damage and CE−corrosion synergy contributes largely to the CE degradation. In other solutions, slight SPC occurs and each material exhibits a mechanical attack- dominated CE mechanism.