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Electrochemically driven C–N bond formation from CO <sub>2</sub> and ammonia at the triple-phase boundary

Junnan Li, Nikolay Kornienko

2022Chemical Science94 citationsDOIOpen Access PDF

Abstract

spectroelectrochemical method, capable of probing the aforementioned gas-liquid-solid boundary, to extract an initial level of mechanistic analysis regarding the reaction pathways of these reactions and the current system's limitations. We believe that the development and understanding of this set of reaction pathways will play significant role in expanding the community's understanding of on-surface electrosynthetic reactions as well as push this set of inherently sustainable technologies towards widespread applicability.

Topics & Concepts

ElectrocatalystElectrolysisElectrochemistryOxygen evolutionAmmoniaElectrosynthesisChemistryFormamideScope (computer science)NanotechnologyMaterials scienceAmmonia productionAcetamideMoleculeElectrochemical energy conversionChemical physicsPhase (matter)Biochemical engineeringElectrolysis of waterElectroplatingBoundary (topology)Combinatorial chemistryInorganic chemistryPhase boundaryGas phaseCO2 Reduction Techniques and CatalystsAmmonia Synthesis and Nitrogen ReductionCarbon dioxide utilization in catalysis
Electrochemically driven C–N bond formation from CO <sub>2</sub> and ammonia at the triple-phase boundary | Litcius