<i>S</i>-Trifluoromethyl thioesters as bifunctional reagents for acyl-trifluoromethylthiolation of alkenes and 1,3-enynes<i>via</i>photoredox/copper dual catalysis
Zhong Zhang, Yang Tian, Xiaowei Li, Zemin Wang, Ruihua Liu, Ping Chen, Xiangqian Li, Jiajia Dai, Dayong Shi
Abstract
Using S -trifluoromethyl thioesters as bifunctional reagents, we developed photoredox/copper dual-catalyzed 1,2-acyl-trifluoromethylthiolation of alkenes and 1,4-acyl-trifluoromethylthiolation of 1,3-enynes.
Topics & Concepts
BifunctionalChemistryReagentTrifluoromethylCopperPhotoredox catalysisCatalysisDual roleCombinatorial chemistryOrganic chemistryPhotocatalysisAlkylFluorine in Organic ChemistrySulfur-Based Synthesis TechniquesInorganic Fluorides and Related Compounds