Ultralow Auger-Assisted Interlayer Exciton Annihilation in WS<sub>2</sub>/WSe<sub>2</sub> Moiré Heterobilayers
Cheng-Syuan Cai, Wei-Yan Lai, P. L. Liu, Tzu-Chieh Chou, Ro-Ya Liu, Chih‐Ming Lin, Shangjr Gwo, Wei‐Ting Hsu
Abstract
High Resolution Image Download MS PowerPoint Slide Transition metal dichalcogenide (TMD) heterobilayers have emerged as a promising platform for exploring solid-state quantum simulators and many-body quantum phenomena. Their type II band alignment, combined with the moiré superlattice, inevitably leads to nontrivial exciton interactions and dynamics. Here, we unveil the distinct Auger annihilation processes for delocalized interlayer excitons in WS 2 /WSe 2 moiré heterobilayers. By fitting the characteristic efficiency droop and bimolecular recombination rate, we quantitatively determine an ultralow Auger coefficient of 1.3 × 10 –5 cm 2 s –1, which is >100-fold smaller than that of excitons in TMD monolayers. In addition, we reveal selective exciton upconversion into the WSe 2 layer, which highlights the significance of intralayer electron Coulomb interactions in dictating the microscopic scattering pathways. The distinct Auger processes arising from spatial electron–hole separation have important implications for TMD heterobilayers while endowing interlayer excitons and their strongly correlated states with unique layer degrees of freedom.