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Complex Refractive Index Spectrum of CsPbBr3 Nanocrystals via the Effective Medium Approximation

Sang-Hyuk Park, Jungwon Kim, Minju Kim, Min Woo Kim, Robert A. Taylor, Kwangseuk Kyhm

2025Nanomaterials6 citationsDOIOpen Access PDF

Abstract

We have estimated the intrinsic complex refractive index spectrum of a CsPbBr3 nanocrystal. With various dilute solutions of CsPbBr3 nanocrystals dissolved in toluene, effective refractive indices were measured at two different wavelengths using Michelson interferometry. Given the effective absorption spectrum of the solution, a full spectrum of the effective refractive index was also obtained through the Kramers–Krönig relations. Based on the Maxwell–Garnett model in the effective medium approximation, the real and imaginary spectrum of the complex refractive index was estimated for the CsPbBr3 nanocrystal, and the dominant inaccuracy was attributed to the size inhomogeneity.

Topics & Concepts

Refractive indexNanocrystalMichelson interferometerWavelengthSpectrum (functional analysis)Materials scienceInterferometryAbsorption (acoustics)Absorption spectroscopyOpticsMolecular physicsOptoelectronicsPhysicsNanotechnologyQuantum mechanicsPerovskite Materials and ApplicationsOptical properties and cooling technologies in crystalline materialsLuminescence Properties of Advanced Materials
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