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Synthesis of δ-phosphorothiolated alcohols by photoredox/copper catalyzed remote C(sp<sup>3</sup>)–H phosphorothiolation of <i>N</i>-alkoxypyridinium salts

Zhipeng Zheng, Shanshan Shi, Qianru Ma, Yufei Yang, Yan Liu, Guo Tang, Yufen Zhao

2021Organic Chemistry Frontiers34 citationsDOI

Abstract

Incorporation of the (RO) 2 P(O)S group through unreactive C(sp 3 )–H phosphorothiolation remains a challenging area of research.

Topics & Concepts

ChemistryCopperCatalysisGroup (periodic table)Medicinal chemistryOrganic chemistrySulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsAdvanced Photocatalysis Techniques
Synthesis of δ-phosphorothiolated alcohols by photoredox/copper catalyzed remote C(sp<sup>3</sup>)–H phosphorothiolation of <i>N</i>-alkoxypyridinium salts | Litcius