Flexible Miniaturized Electrochemical Sensors Based on Multiwalled Carbon Nanotube-Chitosan Nanomaterial for Determination of Nitrite in Soil Solutions
Ana‐Maria Gurban, Lucian-Gabriel Zamfir, Petru Epure, Ioana-Raluca Bunghez, Raluca Senin, Maria-Luiza Jecu, Maria Lorena Jinga, Mihaela Doni
Abstract
Flexible screen-printed electrodes (SPE) were modified in a simple manner with different composite nanomaterials based on carbon allotropes, polymers, and metallic nanoparticles, for amperometric detection of nitrites in soil. Multiwalled carbon nanotubes (MWCNT), chitosan (CS), silver nanoparticles (AgNPs), 1,8-diaminonaphthalene (1,8-DAN), and a sol-gel (SG) matrix were used for modification of the carbon paste working electrodes. Sensitive and selective detection of nitrite was achieved by using a MWCNT-CS-modified sensor, in acetate buffer at pH 5, at an applied potential of 0.58 V vs. Ag/AgCl. The MWCNT-CS-based sensor displayed a specific sensitivity of 204.4 mA·M−1·cm−2, with a detection limit of 2.3 µM (S/N = 3) in a linear range up to 1.7 mM, showing good stability, reproducibility, and selectivity towards other interfering species. A miniaturized portable system using the developed flexible electrochemical MWCNT-CS-based sensors was dedicated for the detection of nitrite in different samples of soil solutions extracted by using suction lysimeters.