Measuring the Pseudocapacitive Behavior of Individual V<sub>2</sub>O<sub>5</sub> Particles by Scanning Electrochemical Cell Microscopy
Cong Gao, Yingjian Li, Jiao Zhao, Wei Sun, Shanyi Guang, Qianjin Chen
Abstract
V 2 O 5 is a promising pseudocapacitive material for electrochemical energy storage with balanced power and energy density. Understanding the charge-storage mechanism is of significance to further improve the rate performance. Here, we report an electrochemical study of individual V 2 O 5 particles using scanning electrochemical cell microscopy with colocalized electron microscopy. A carbon sputtering procedure is proposed for the pristine V 2 O 5 particles to improve their structure stability and electronic conductivity. The achieved high-quality electrochemical cyclic voltammetry results, structural integrity, and high oxidation to reduction charge ratio (as high as 97.74%) assured further quantitative analysis of the pseudocapacitive behavior of single particles and correlation with local particle structures. A broad range of capacitive contribution is revealed, with an average ratio of 76% at 1.0 V/s. This study provides new opportunities for quantitative analysis of the electrochemical charge-storage process at single particles, especially for electrode materials with electrolyte-induced instability.