Development of poly(vinylidene fluoride)/thermoplastic polyurethane/carbon black‐polypyrrole composites with enhanced piezoelectric properties
Mayara C. Bertolini, Nico Zamperlin, Guilherme Mariz de Oliveira Barra, Alessandro Pegoretti
Abstract
Abstract Poly(vinylidene fluoride)/thermoplastic polyurethane (PVDF/TPU) composites filled with carbon‐black polypyrrole were prepared via melt compounding followed by compression molding and fused filament fabrication. CB‐PPy was added to the blends from 0 up to 15% to possible act as nucleating filler for PVDF β phase in order to increase its piezoelectric response. The influence of blending PVDF and TPU and of the addition of CB‐PPy on the overall crystallinity, content of β phase, and piezoelectric response of composites were investigated by differential scanning calorimetry (DSC), Fourier‐transformed infrared spectroscopy (FTIR), X‐ray diffraction (XRD) and determination of the piezoelectric coefficient ( d 33 ). It was found that the addition of TPU to PVDF induced an increase of the crystallinity degree and content of β phase in PVDF. Moreover, although the degree of crystallinity of the composites decreased with the addition of CB‐PPy, the percentage of β phase in PVDF was increased. This effect is more significant in samples with filler concentration higher than 6 wt%. As expected, the d 33 of the composites increased as the content of the β phase increased. Furthermore, 3D printed samples displayed lower content of β phase and reduced piezoelectric responses when compared to compression molded samples with same composition.