Strong second order nonlinear optical properties of azulene-based porphyrin derivatives
Cuicui Yang, Li Li, Wei Quan Tian, Weiqi Li, Ling Yang
Abstract
esu). A novel strategy to stabilize the electronic structures as well as maintain good second order NLO responses by introducing appropriate metals into the azulene-fused porphyrins is extendable to other similar systems. Strong sum frequency generation and different frequency generations of those azulene-fused porphyrins in visible and near-infrared regions may inspire experimental exploration and related applications of azulene-based porphyrins particularly in biological nonlinear optics.
Topics & Concepts
AzulenePorphyrinHyperpolarizabilityDensity functional theoryChemistryComputational chemistryAtom (system on chip)FlosDerivative (finance)PhotochemistryMaterials scienceMoleculeCombinatorial chemistryOrganic chemistryComputer scienceEconomicsPolarizabilityFinancial economicsRutinEmbedded systemAntioxidantPorphyrin and Phthalocyanine ChemistryNonlinear Optical Materials ResearchSynthesis and Properties of Aromatic Compounds